Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C–H Bonds
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چکیده
منابع مشابه
Tuning the Reactivity of Fe(O) toward C−H Bonds at Room Temperature: Effect of Water
The presence of an Fe(O) species has been postulated as the active intermediate for the oxidation of both C−H and CC bonds in the Rieske dioxygenase family of enzymes. Understanding the reactivity of these high valent iron−oxo intermediates, especially in an aqueous medium, would provide a better understanding of these enzymatic reaction mechanisms. The formation of an Fe(O) complex at room te...
متن کاملTuning the Reactivity of FeV(O) toward C–H Bonds at Room Temperature: Effect of Water
The presence of an Fe(V)(O) species has been postulated as the active intermediate for the oxidation of both C-H and C═C bonds in the Rieske dioxygenase family of enzymes. Understanding the reactivity of these high valent iron-oxo intermediates, especially in an aqueous medium, would provide a better understanding of these enzymatic reaction mechanisms. The formation of an Fe(V)(O) complex at r...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2014
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja412537m